FIRE OR EXPLOSION
* EXTREMELY FLAMMABLE. * Will be easily ignited by heat, sparks or flames. * Will form explosive mixtures with air. * Vapors from liquefied gas are initially heavier than air and spread along ground. * Vapors may travel to source of ignition and flash back. * Containers may explode when heated. * Ruptured cylinders may rocket.
HEALTH
* Vapors may cause dizziness or asphyxiation without warning. * Some may be irritating if inhaled at high concentrations. * Contact with gas or liquefied gas may cause burns, severe injury and/or frostbite. * Fire may produce irritating and/or toxic gases.
PUBLIC SAFETY
* CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. * Isolate spill or leak area immediately for at least 50 to 100 meters (160 to 330 feet) in all directions. * Keep unauthorized personnel away. * Stay upwind. * Many gases are heavier than air and will spread along ground and collect in low or confined areas (sewers, basements, tanks). * Keep out of low areas.
PROTECTIVE CLOTHING
* Wear positive pressure self-contained breathing apparatus (SCBA). * Structural firefighters' protective clothing will only provide limited protection. * Always wear thermal protective clothing when handling refrigerated/cryogenic liquids.
EVACUATION
Large Spill: Consider initial downwind evacuation for at least 800 meters (1/2 mile).
Fire: If tank, rail car or tank truck is involved in a fire, ISOLATE for 1600 meters (1 mile) in all directions; also, consider initial evacuation for 1600 meters (1 mile) in all directions.
FIRE
* DO NOT EXTINGUISH A LEAKING GAS FIRE UNLESS LEAK CAN BE STOPPED.
Small Fires: Dry chemical or CO2.
Large Fires: * Water spray or fog. * Move containers from fire area if you can do it without risk.
Fire involving Tanks: * Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. * Cool containers with flooding quantities of water until well after fire is out. * Do not direct water at source of leak or safety devices; icing may occur. * Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. * ALWAYS stay away from tanks engulfed in fire. * For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible, withdraw from area and let fire burn.
SPILL OR LEAK
* ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). * All equipment used when handling the product must be grounded. * Do not touch or walk through spilled material. * Stop leak if you can do it without risk. * If possible, turn leaking containers so that gas escapes rather than liquid. * Use water spray to reduce vapors or divert vapor cloud drift. Avoid allowing water runoff to contact spilled material. * Do not direct water at spill or source of leak. * Prevent spreading of vapors through sewers, ventilation systems and confined areas. * Isolate area until gas has dispersed.
CAUTION: When in contact with refrigerated/cryogenic liquids, many materials become brittle and are likely to break without warning.
FIRST AID
* Move victim to fresh air. * Call 911 or emergency medical service. * Apply artificial respiration if victim is not breathing. * Administer oxygen if breathing is difficult. * Remove and isolate contaminated clothing and shoes. * Clothing frozen to the skin should be thawed before being removed. * In case of contact with liquefied gas, thaw frosted parts with lukewarm water * Keep victim warm and quiet. * Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves.