134 Flammable Solids - Toxic and/or Corrosive                                         hpbutton.gif (1641 bytes)

POTENTIAL HAZARDS

FIRE OR EXPLOSION

* Flammable/combustible material. * May be ignited by heat, sparks or flames. * When heated, vapors may form explosive mixtures with air: indoors, outdoors, and sewers explosion hazards. * Contact with metals may evolve flammable hydrogen gas. * Containers may explode when heated.

HEALTH

* TOXIC; inhalation, ingestion, or skin contact with material may cause severe injury or death. * Fire will produce irritating, corrosive and/or toxic gases. * Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.

PUBLIC SAFETY

* CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. * Isolate spill or leak area immediately for at least 25 to 50 meters (80 to 160 feet) in all directions. * Stay upwind. * Keep unauthorized personnel away. * Keep out of low areas. * Ventilate enclosed areas.

PROTECTIVE CLOTHING

* Wear positive pressure self-contained breathing apparatus (SCBA). * Wear chemical protective clothing which is specifically recommended by the manufacturer. It may provide little or no thermal protection. * Structural firefighters' protective clothing provides limited protection in fire situations ONLY; it is not effective in spill situations.

EVACUATION

Large Spill:  Consider initial downwind evacuation for at least 100 meters (330 feet).

Fire:   If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions.

EMERGENCY RESPONSE

FIRE

Small Fires:  Dry chemical, CO2, water spray or alcohol-resistant foam.

Large Fires:  * Water spray, fog or alcohol-resistant foam. * Move containers from fire area if you can do it without risk. * Use water spray or fog; do not use straight streams. * Do not get water inside containers. * Dike fire control water for later disposal; do not scatter the material.

Fire involving Tanks or Car/Trailer Loads:  * Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. * Cool containers with flooding quantities of water until well after fire is out. * Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. * ALWAYS stay away from tanks engulfed in fire.

SPILL OR LEAK

* Fully encapsulating, vapor protective clothing should be worn for spills and leaks with no fire. * ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). * Stop leak if you can do it without risk. * Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. * Prevent entry into waterways, sewers, basements or confined areas. * Use clean non-sparking tools to collect material and place it into loosley covered plastic containers for later disposal.

FIRST AID

* Move victim to fresh air. * Call 911 or emergency medical service. * Apply artificial respiration if victim is not breathing. * Do not use mouth-to-mouth method if victim ingested or inhaled the substance; induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. * Administer oxygen if breathing is difficult. * Remove and isolate contaminated clothing and shoes. * In case of contact with substance, immediately flush skin or eyes with running water for at least 20 minutes. * For minor skin contact, avoid spreading material on unaffected skin. * Keep victim warm and quiet. * Effects of exposure (inhalation, ingestion or skin contact) to substance may be delayed. * Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves.

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