134 Flammable Solids - Toxic and/or
Corrosive
 |
| POTENTIAL HAZARDS |
FIRE
OR EXPLOSION |
*
Flammable/combustible material. * May be ignited by heat, sparks or flames. * When heated,
vapors may form explosive mixtures with air: indoors, outdoors, and sewers explosion
hazards. * Contact with metals may evolve flammable hydrogen gas. * Containers may explode
when heated. |
HEALTH |
*
TOXIC; inhalation, ingestion, or skin contact with material may cause severe injury or
death. * Fire will produce irritating, corrosive and/or toxic gases. * Runoff from fire
control or dilution water may be corrosive and/or toxic and cause pollution. |
PUBLIC
SAFETY |
*
CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not
available or no answer, refer to appropriate telephone number listed on the inside back
cover. * Isolate spill or leak area immediately for at least 25 to 50 meters (80 to 160
feet) in all directions. * Stay upwind. * Keep unauthorized personnel away. * Keep out of
low areas. * Ventilate enclosed areas. |
PROTECTIVE
CLOTHING |
*
Wear positive pressure self-contained breathing apparatus (SCBA). * Wear chemical
protective clothing which is specifically recommended by the manufacturer. It may provide
little or no thermal protection. * Structural firefighters' protective clothing provides
limited protection in fire situations ONLY; it is not effective in spill situations. |
EVACUATION |
Large
Spill: Consider initial downwind evacuation for at least 100 meters (330 feet). |
Fire:
If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2
mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in
all directions. |
| EMERGENCY RESPONSE |
FIRE |
Small
Fires: Dry chemical, CO2, water spray or alcohol-resistant foam. |
Large
Fires: * Water spray, fog or alcohol-resistant foam. * Move containers from fire
area if you can do it without risk. * Use water spray or fog; do not use straight streams.
* Do not get water inside containers. * Dike fire control water for later disposal; do not
scatter the material. |
Fire
involving Tanks or Car/Trailer Loads: * Fight fire from maximum distance or use
unmanned hose holders or monitor nozzles. * Cool containers with flooding quantities of
water until well after fire is out. * Withdraw immediately in case of rising sound from
venting safety devices or discoloration of tank. * ALWAYS stay away from tanks engulfed in
fire. |
SPILL
OR LEAK |
*
Fully encapsulating, vapor protective clothing should be worn for spills and leaks with no
fire. * ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate
area). * Stop leak if you can do it without risk. * Do not touch damaged containers or
spilled material unless wearing appropriate protective clothing. * Prevent entry into
waterways, sewers, basements or confined areas. * Use clean non-sparking tools to collect
material and place it into loosley covered plastic containers for later disposal. |
FIRST
AID |
*
Move victim to fresh air. * Call 911 or emergency medical service. * Apply artificial
respiration if victim is not breathing. * Do not use mouth-to-mouth method if victim
ingested or inhaled the substance; induce artificial respiration with the aid of a pocket
mask equipped with a one-way valve or other proper respiratory medical device. *
Administer oxygen if breathing is difficult. * Remove and isolate contaminated clothing
and shoes. * In case of contact with substance, immediately flush skin or eyes with
running water for at least 20 minutes. * For minor skin contact, avoid spreading material
on unaffected skin. * Keep victim warm and quiet. * Effects of exposure (inhalation,
ingestion or skin contact) to substance may be delayed. * Ensure that medical personnel
are aware of the material(s) involved, and take precautions to protect themselves. |
