136 Substances - Spontaneously Combustible -
Toxic (Air-Reactive)  |
| POTENTIAL HAZARDS |
FIRE
OR EXPLOSION |
*
Extremely flammable; will ignite itself if exposed to air. * Burns rapidly, releasing
dense, white, irritating fumes. *
Substance may be transported in a molten form. * May re-ignite after fire is extinguished. |
HEALTH |
*
Fire will produce irritating, corrosive and/or toxic gases. * TOXIC; ingestion of
substance or inhalation of decomposition products will cause severe injury or death. *
Contact with substance may cause severe burns to skin and eyes. * Some effects may be
experienced due to skin absorption. * Runoff from fire control may be corrosive and/or
toxic and cause pollution. |
PUBLIC
SAFETY |
*
CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not
available or no answer, refer to appropriate telephone number listed on the inside back
cover. * Isolate spill or leak area immediately for at least 100 to 150 meters (330 to 490
feet) in all directions. * Stay upwind. * Keep unauthorized personnel away. * Keep out of
low areas. |
PROTECTIVE
CLOTHING |
*
Wear positive pressure self-contained breathing apparatus (SCBA). * Wear chemical
protective clothing which is specifically recommended by the manufacturer. It may provide
little or no thermal protection. * Structural firefighters' protective clothing provides
limited protection in fire situations ONLY; it is not effective in spill situations. |
EVACUATION |
Spill:
Consider initial downwind evacuation for at least 300 meters (1000 feet). |
Fire:
If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2
mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in
all directions. |
| EMERGENCY RESPONSE |
FIRE |
Small
Fires: Water spray, wet sand or wet earth. |
Large
Fires: * Water spray or fog. * Do not scatter spilled material with high pressure
water streams. * Move containers from fire area if you can do it without risk. |
Fire
involving Tanks or Car/Trailer Loads: * Fight fire from maximum distance or use
unmanned hose holders or monitor nozzles. * Cool containers with flooding quantities of
water until well after fire is out. * Withdraw immediately in case of rising sound from
venting safety devices or discoloration of tank. * ALWAYS stay away from tanks engulfed in
fire. |
SPILL
OR LEAK |
*
Fully encapsulating, vapor protective clothing should be worn for spills and leaks with no
fire. * ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate
area). * Do not touch or walk through spilled material. * Do not touch damaged containers
or spilled material unless wearing appropriate protective clothing. * Stop leak if you can
do it without risk. |
Small
Spills: Cover with water, sand or earth. Shovel into metal container and keep
material under water. |
Large
Spills: * Dike for later disposal and cover with wet sand or earth. * Prevent entry
into waterways, sewers, basements or confined areas. |
FIRST
AID |
*
Move victim to fresh air. * Call 911 or emergency medical service. * Apply artificial
respiration if victim is not breathing. * Administer oxygen if breathing is difficult. *
In case of contact with substance, keep exposed skin areas immersed in water or covered
with wet bandages until medical attention is received. * Removal of solidified molten
material from skin requires medical assistance. * Remove and isolate contaminated clothing
and shoes at the site and place in metal container filled with water. Fire hazard if
allowed to dry. * Effects of exposure (inhalation, ingestion or skin contact) to substance
may be delayed. * Keep victim warm and quiet. * Ensure that medical personnel are aware of
the material(s) involved, and take precautions to protect themselves. |
