FIRE OR EXPLOSION
* These substances will accelerate burning when involved in a fire. * May explode from heat or contamination. * Some may burn rapidly. * Some will react explosively with hydrocarbons (fuels). * May ignite combustibles (wood, paper, oil, clothing, etc.). * Containers may explode when heated. * Runoff may create fire or explosion hazard.
HEALTH
* Toxic by ingestion. * Inhalation of dust is toxic. * Fire may produce irritating, corrosive and/or toxic gases. * Contact with substance may cause severe burns to skin and eyes. * Runoff from fire control or dilution water may cause pollution.
PUBLIC SAFETY
* CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. * Isolate spill or leak area immediately for at least 10 to 25 meters (30 to 80 feet) in all directions. * Keep unauthorized personnel away. * Stay upwind. * Keep out of low areas. * Ventilate closed spaces before entering.
PROTECTIVE CLOTHING
* Wear positive pressure self-contained breathing apparatus (SCBA). * Wear chemical protective clothing which is specifically recommended by the manufacturer. It may provide little or no thermal protection. * Structural firefighters' protective clothing will only provide limited protection.
EVACUATION
Large Spill: Consider initial downwind evacuation for at least 100 meters (330 feet).
Fire: If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions.
FIRE
Small Fires: Use water. Do not use dry chemicals or foams. CO2 or Halon may provide limited control.
Large Fires: * Flood fire area with water from a distance. * Move containers from fire area if you can do it without risk. * Do not move cargo or vehicle if cargo has been exposed to heat. * Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. * Cool containers with flooding quantities of water until well after fire is out. * ALWAYS stay away from tanks engulfed in fire. * For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible, withdraw from area and let fire burn.
SPILL OR LEAK
* Keep combustibles (wood, paper, oil, etc.) away from spilled material. * Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. * Stop leak if you can do it without risk.
Small Dry Spills: With clean shovel place material into clean, dry container and cover loosely; move containers from spill area.
Large Spills: Dike far ahead of spill for later disposal.
FIRST AID
* Move victim to fresh air. * Call 911 or emergency medical service. * Apply artificial respiration if victim is not breathing. * Administer oxygen if breathing is difficult. * Remove and isolate contaminated clothing and shoes. * In case of contact with substance, immediately flush skin or eyes with running water for at least 20 minutes. * Keep victim warm and quiet. * Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves.