146 Organic Peroxides (Heat, Contamination
and Friction Sensitive)  |
| POTENTIAL HAZARDS |
FIRE
OR EXPLOSION |
*
May explode from heat, shock, friction or contamination. * May ignite combustibles (wood,
paper, oil, clothing, etc.). * May be ignited by heat, sparks or flames. * May burn
rapidly with flare-burning effect. * Containers may explode when heated. * Runoff may
create fire or explosion hazard. |
HEALTH |
*
Fire may produce irritating, corrosive and/or toxic gases. * Ingestion or contact (skin,
eyes) with substance may cause severe injury or burns. * Runoff from fire control or
dilution water may cause pollution. |
PUBLIC
SAFETY |
*
CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not
available or no answer, refer to appropriate telephone number listed on the inside back
cover. * Isolate spill or leak area immediately for at least 25 to 50 meters (80 to 160
feet) in all directions. * Keep unauthorized personnel away. * Stay upwind. * Keep out of
low areas. |
PROTECTIVE
CLOTHING |
*
Wear positive pressure self-contained breathing apparatus (SCBA). * Wear chemical
protective clothing which is specifically recommended by the manufacturer. It may provide
little or no thermal protection. * Structural firefighters' protective clothing will only
provide limited protection. |
EVACUATION |
Large
Spill: Consider initial evacuation for at least 250 meters (800 feet). |
Fire:
If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2
mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in
all directions. |
| EMERGENCY RESPONSE |
FIRE |
Small
Fires: Water spray or fog is preferred; if water not available use dry chemical, CO2
or regular foam. |
Large
Fires: * Flood fire area with water from a distance. * Use water spray or fog; do
not use straight streams. * Move containers from fire area if you can do it without risk.
* Do not move cargo or vehicle if cargo has been exposed to heat. * Fight fire from
maximum distance or use unmanned hose holders or monitor nozzles. * Cool containers with
flooding quantities of water until well after fire is out. * ALWAYS stay away from tanks
engulfed in fire. * For massive fire, use unmanned hose holders or monitor nozzles; if
this is impossible, withdraw from area and let fire burn. |
SPILL
OR LEAK |
*
ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). *
Keep combustibles (wood, paper, oil, etc.) away from spilled material. * Do not touch
damaged containers or spilled material unless wearing appropriate protective clothing. *
Keep substance wet using water spray. * Stop leak if you can do it without risk. |
Small
Spills: Take up with inert, damp, noncombustible material using clean non-sparking
tools and place into loosely covered plastic containers for later disposal. |
Large
Spills: * Wet down with water and dike for later disposal. * Prevent entry into
waterways, sewers, basements or confined areas. * DO NOT CLEAN-UP OR DISPOSE OF, EXCEPT
UNDER SUPERVISION OF A SPECIALIST. |
FIRST
AID |
*
Move victim to fresh air. * Call 911 or emergency medical service. * Apply artificial
respiration if victim is not breathing. * Administer oxygen if breathing is difficult. *
Remove and isolate contaminated clothing and shoes. * Remove material from skin
immediately. * In case of contact with substance, immediately flush skin or eyes with
running water for at least 20 minutes. * Keep victim warm and quiet. * Ensure that medical
personnel are aware of the material(s) involved, and take precautions to protect
themselves. |
