150 Substances (Self-Reactive/Temperature
Controlled)
 |
| POTENTIAL HAZARDS |
FIRE
OR EXPLOSION |
*
Self-accelerating decomposition may occur if the specific control. * Self-decomposition or
self-ignition may be triggered by heat, chemical reaction, friction or impact temperature
is not maintained. * These materials are particularly sensitive to temperature rises.
Above a given "Control Temperature" they decompose violently and catch fire. *
May be ignited by heat, sparks or flames. * Some may decompose explosively when heated or
involved in a fire. * May burn violently. Decomposition may be self-accelerating and
produce large amounts of gases. * Vapors or dust may form explosive mixtures with air. |
HEALTH |
*
Inhalation or contact with vapors, substance, or decomposition products may cause severe
injury or death. * May produce irritating, toxic and/or corrosive gases. * Runoff from
fire control may cause pollution. |
PUBLIC
SAFETY |
*
CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not
available or no answer, refer to appropriate telephone number listed on the inside back
cover. * Isolate spill or leak area immediately for at least 50 to 100 meters (160 to 330
feet) in all directions. * Keep unauthorized personnel away. * Stay upwind. * Keep out of
low areas. * DO NOT allow the substance to warm up. Obtain liquid nitrogen, dry ice or ice
for cooling. If none can be obtained, evacuate the area immediately. |
PROTECTIVE
CLOTHING |
*
Wear positive pressure self-contained breathing apparatus (SCBA). * Wear chemical
protective clothing which is specifically recommended by the manufacturer. It may provide
little or no thermal protection. * Structural firefighters' protective clothing will only
provide limited protection. |
EVACUATION |
Large
Spill: Consider initial downwind evacuation for at least 250 meters (800 feet). |
Fire:
If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2
mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in
all directions. |
| EMERGENCY RESPONSE |
FIRE |
*
The temperature of the substance must be maintained at or below the "Control
Temperature" at all times. |
Small
Fires: Dry chemical, CO2, water spray or regular foam. |
Large
Fires: * Flood fire area with water from a distance. * Move containers from fire
area if you can do it without risk. |
Fire
involving Tanks or Car/Trailer Loads: * BEWARE OF POSSIBLE CONTAINER EXPLOSION. *
Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. * Cool
containers with flooding quantities of water until well after fire is out. * Withdraw
immediately in case of rising sound from venting safety devices or discoloration of tank.
* ALWAYS stay away from tanks engulfed in fire. |
SPILL
OR LEAK |
*
ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). *
Do not touch or walk through spilled material. * Stop leak if you can do it without risk. |
Small
Spills: * Take up with inert, damp, noncombustible material using clean non-sparking
tools and place into loosely covered plastic containers for later disposal. * Prevent
entry into waterways, sewers, basements or confined areas. * DO NOT CLEAN-UP OR DISPOSE
OF, EXCEPT UNDER SUPERVISION OF A SPECIALIST. |
FIRST
AID |
*
Move victim to fresh air. * Call 911 or emergency medical service. * Apply artificial
respiration if victim is not breathing. * Administer oxygen if breathing is difficult. *
Remove and isolate contaminated clothing and shoes. * In case of contact with substance,
immediately flush skin or eyes with running water for at least 20 minutes. * Keep victim
warm and quiet. * Ensure that medical personnel are aware of the material(s) involved, and
take precautions to protect themselves. |
