HEALTH
* Inhalation of vapors or dust is extremely irritating. * May cause burning of eyes and flow of tears. * May cause coughing, difficult breathing and nausea. * Brief exposure effects last only a few minutes. * Exposure in an enclosed area may be very harmful. * Fire will produce irritating, corrosive and/or toxic gases. * Runoff from fire control or dilution water may cause pollution.
FIRE OR EXPLOSION
* Some of these materials may burn, but none ignite readily. * Containers may explode when heated.
PUBLIC SAFETY
* CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. * Isolate spill or leak area immediately for at least 25 to 50 meters (80 to 160 feet) in all directions. * Keep unauthorized personnel away. * Stay upwind. * Keep out of low areas. * Ventilate closed spaces before entering.
PROTECTIVE CLOTHING
* Wear positive pressure self-contained breathing apparatus (SCBA). * Wear chemical protective clothing which is specifically recommended by the manufacturer. It may provide little or no thermal protection. * Structural firefighters' protective clothing provides limited protection in fire situations ONLY; it is not effective in spill situations.
EVACUATION
Large Spill: Consider initial downwind evacuation for at least 100 meters (330 feet).
Fire: If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions.
FIRE
Small Fires: Dry chemical, CO2, water spray or regular foam.
Large Fires: * Water spray, fog or regular foam. * Move containers from fire area if you can do it without risk. * Dike fire control water for later disposal; do not scatter the material.
Fire involving Tanks or Car/Trailer Loads: * Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. * Do not get water inside containers. * Cool containers with flooding quantities of water until well after fire is out. * Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. * ALWAYS stay away from tanks engulfed in fire. * For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible, withdraw from area and let fire burn.
SPILL OR LEAK
* Do not touch or walk through spilled material. * Stop leak if you can do it without risk. * Fully encapsulating, vapor protective clothing should be worn for spills and leaks with no fire.
Small Spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal.
Large Spills: * Dike far ahead of liquid spill for later disposal. * Prevent entry into waterways, sewers, basements or confined areas.
FIRST AID
* Move victim to fresh air. * Call 911 or emergency medical service. * Apply artificial respiration if victim is not breathing. * Do not use mouth-to-mouth method if victim ingested or inhaled the substance; induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. * Administer oxygen if breathing is difficult. * Remove and isolate contaminated clothing and shoes. * In case of contact with substance, immediately flush skin or eyes with running water for at least 20 minutes. * For minor skin contact, avoid spreading material on unaffected skin. * Keep victim warm and quiet. * Effects should disappear after individual has been exposed to fresh air for approximately 10 minutes. * Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves.