166 Radioactive Materials - Corrosive
 |
| (Uranium
Hexafluoride/Water-Sensitive) |
|
| POTENTIAL HAZARDS |
HEALTH |
*
Radiation presents minimal risk to transport workers, emergency response personnel, and
the public during transportation accidents. Packaging durability increases as potential
radiation and criticality hazards of the content increase. * Chemical hazard greatly
exceeds radiation hazard. * Substance reacts with water and water vapor in air to form
toxic and corrosive hydrogen fluoride gas and an extremely irritating and corrosive,
white-colored, water-soluble residue. * If inhaled, may be fatal. * Direct contact causes
burns to skin, eyes, and respiratory tract. * Low-level radioactive material; very low
radiation hazard to people. * Runoff from control of cargo fire may cause low-level
pollution. |
FIRE
OR EXPLOSION |
*
Substance does not burn. * Containers in protective overpacks (horizontal cylindrical
shape with short legs for tie-downs), are identified with "AF" or
"B(U)F" on shipping papers or by markings on the overpacks. They are designed
and evaluated to withstand severe conditions including total engulfment in flames at
temperatures of 800 degrees C (1475 degrees F). * Bare filled cylinders, identified with
UN2978 as part of the marking, may rupture in heat of engulfing fire; bare empty (except
for residue) cylinders will not rupture in fires. * The material may react violently with
fuels. * Radioactivity does not change
flammability or other properties of materials. |
PUBLIC
SAFETY |
*
CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not
available or no answer, refer to appropriate telephone number listed on the inside back
cover. * Priorities for rescue, life-saving, first aid, and control of fire and other
hazards are higher than the priority for measuring radiation levels. * Radiation Authority
must be notified of accident conditions. Radiation Authority is usually responsible for
decisions about radiological consequences and closure of emergencies. * Isolate spill or
leak area immediately for at least 25 to 50 meters (80 to 160 feet) in all directions. *
Stay upwind. * Keep unauthorized personnel away. * Detain or isolate uninjured persons or
equipment suspected to be contaminated; delay decontamination and cleanup until
instructions are received from Radiation Authority. |
PROTECTIVE
CLOTHING |
*
Wear positive pressure self-contained breathing apparatus (SCBA). * Wear chemical
protective clothing which is specifically recommended by the manufacturer. It may provide
little or no thermal protection. * Structural firefighters' protective clothing provides
limited protection in fire situations ONLY; it is not effective in spill situations. |
EVACUATION |
Large
Spill: Consider initial downwind evacuation for at least 100 meters (330 feet). |
Fire:
When a large quantity of this material is involved in a major fire, consider an
initial evacuation distance of 300 meters (1000 feet) in all directions. |
| EMERGENCY RESPONSE |
FIRE |
*
DO NOT USE WATER OR FOAM ON MATERIAL ITSELF. * Move containers from fire area if you can
do it without risk. |
Small
Fires: Dry chemical or CO2. |
Large
Fires: * Water spray, fog or regular foam. * Cool containers with flooding
quantities of water until well after fire is out. * If this is impossible, withdraw from
area and let fire burn. * ALWAYS stay away from tanks engulfed in fire. |
SPILL
OR LEAK |
*
Do not touch damaged packages or spilled material. * Without fire or smoke, leak will be
evident by visible and irritating vapors and residue forming at the point of release. *
Use fine water spray to reduce vapors; do not put water directly on point of material
release from container. * Residue buildup may self-seal small leaks. * Dike far ahead of
spill to collect runoff water. |
FIRST
AID |
*
Medical problems take priority over radiological concerns. * Use first aid treatment
according to the nature of the injury. * Do not delay care and transport of a seriously
injured person. * Apply artificial respiration if victim is not breathing. * Administer
oxygen if breathing is difficult. * In case of contact with substance, immediately flush
skin or eyes with running water for at least 20 minutes. * Effects of exposure
(inhalation, ingestion or skin contact) to substance may be delayed. * Injured persons
contaminated by contact with released material are not a serious hazard to health care
personnel, equipment or facilities. * Ensure that medical personnel are aware of the
material(s) involved, take precautions to protect themselves and prevent spread of
contamination. |
